In the material coating industry always employment organic solvents, but in that location be several disadvantages much(prenominal) as environmental problem.Our research try to avoid those by employ Supercritical Carbon Dioxide (SC-CO2) as solvent of N-Octacosane ( C28) to recall Superhydrophobic acrylate resin heightens by a Rapidly Expanding Supercritical resolving force out (RESS) method. In the previous work, SC-CO2, Superhydrophobic locates properties and RESS method leave been canvass. For the generation of Superhydrophobic surface have to know the residue clipping of diffusion and the solvability of N-Octacosane in SC-CO2. Hence, in the present work, the diffusivity and the solubility of N-Octacosane in SC-CO2 have been studied to determine equilibrium time and optimum conditions that raise be operate in our laboratory (Limited push cl barrier ). [1] has been presented diffusion coefficient by wax diffusing by the drudge sphere surfaces at temperatu re 40 -70 ?C, pressure 93 -150 bar, there are diffusion coefficient 6.0Ã10-11 - 1.1Ã10-9 cm2/s and equilibrium time some 5-10 hour.
[2] have measured solubility of N-Octacosane by using a semi-flow phase equilibrium apparatus at temperature 35- 55 ?C, pressure 100-150 bar, there are solubility (mole fraction) 3.9Ã10-4 - 8.6Ã10-3. These values are acceptable, so the optimum condition for our laboratory was selected at the equilibrium time, supercritical conditions of SC-CO2 and below melting point of N-Octacosane are 40 - 55 ?C and 100 -150 bar. We are expected that at those conditions leave behind be gener ate suitable morphology, contact slant and ! correct more superhydrophobic behavior.If you want to get a profuse essay, mold it on our website: BestEssayCheap.com
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